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- W2085927617 abstract "Crystal structures and low field principal crystal axis magnetic measurements are reported for the antiferromagnetic iron (III) salts A2FeCl5⋅H2O; A=Rb+, Cs+. The two compounds undergo a zero field paramagnetic to antiferromagnetic phase transition at 6.5 K (A=Cs+) and 10.05 K (A=Rb+). The spin flop magnetic phase is observed in high field measurements. The magnetic field-temperature phase diagrams are reported. All magnetic measurements were recorded on a superconducting susceptometer. The bicritical points are 6.25 K, 14.5 kOe (A=Cs+), 9.75 K, 17.8 KOe (A=Rb+). Crystal data for Cs2FeCl5⋅H2O: space group Cmcm, Z=4, a=7.442(3) Å, b=17.307(7) Å, c=8.077(7) Å, V=1040 Å3, R=5.2%, 561 reflections. Crystal data for Rb2FeCl5⋅H2O, space group Pnma, Z=4, a=13.825(4) Å, b=9.918(3) Å, c=7.100(2) Å, V=4.9 Å3, 5.7%, 712 reflections." @default.
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- W2085927617 date "1979-06-01" @default.
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- W2085927617 title "Crystal structures of A2FeCl5⋅H2O (A=Rb+, Cs+) and field dependent superconducting susceptometer measurements" @default.
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- W2085927617 doi "https://doi.org/10.1063/1.437357" @default.
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