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- W2085954740 abstract "The synthesis of methyl butyrate and octyl acetate through immobilized Rhizopus oryzae NRRL 3562 lipase mediated transesterification was studied under solvent-free conditions. The effect of different transesterification variables, namely, molarity of alcohol, reaction time, temperature, agitation, addition of water, and enzyme amount on molar conversion (%) was investigated. A maximum molar conversion of 70.42% and 92.35% was obtained in a reaction time of 14 and 12 h with the transesterification variables of 0.6 M methanol in vinyl butyrate and 2 M octanol in vinyl acetate using 80 U and 60 U immobilized lipase with the agitation speed of 200 rpm and 0.2% water addition at 32°C and 36°C for methyl butyrate and octyl acetate, respectively. The immobilized enzyme has retained good relative activity (more than 95%) up to five and six recycles for methyl butyrate and octyl acetate, respectively. Hence, the present investigation makes a great impingement in natural flavour industry by introducing products synthesized under solvent-free conditions to the flavour market." @default.
- W2085954740 created "2016-06-24" @default.
- W2085954740 creator A5033376186 @default.
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- W2085954740 date "2013-05-30" @default.
- W2085954740 modified "2023-09-30" @default.
- W2085954740 title "Solvent-Free Synthesis of Flavour Esters through Immobilized Lipase Mediated Transesterification" @default.
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- W2085954740 doi "https://doi.org/10.1155/2013/367410" @default.
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