FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085963223> ?p ?o ?g. }

• W2085963223 endingPage "156" @default.
• W2085963223 startingPage "145" @default.
• W2085963223 abstract "A method, not demanding calibration with standard solutions of the analysed ions, is proposed for the determination of lead and copper in synthetic and real samples, by employing thin mercury film electrodes formed onto carbon disc microelectrodes. The method is based on an equation derived by exploiting the characteristics of the in situ thin mercury film formation and steady state currents achievable at microelectrodes. The conditions under which this equation is applicable are examined. In particular the effects of the nature of the electrolyte, with particular concern towards chloride ions, ionic strength and pH of the medium are investigated. The validity of the proposed method is verified on synthetic aqueous solutions. It is shown that the method can be applied to samples characterised either by a low or high ionic strength, while the solutions must be acidic (pH < 6 is recommended) and should not contain more than 1 mM of chloride ions. Real samples, as well water and rain, under conditions fulfilling the above prescriptions, are also investigated. The comparison of data obtained employing the proposed method with those taken, or evaluated by using classical calibration procedures with standard solutions, shows that agreement within 11% is found for 2 and 0.6 μg l−1 levels for lead and copper, respectively, with a relative standard deviation of about 6%. For 10 and 3 μg l−1 levels of lead and copper, respectively, which are the average values in the real samples investigated, both accuracy and RSD are around 5%." @default.
• W2085963223 created "2016-06-24" @default.
• W2085963223 creator A5000158309 @default.
• W2085963223 creator A5069536623 @default.
• W2085963223 creator A5077034519 @default.
• W2085963223 date "1997-07-01" @default.
• W2085963223 modified "2023-10-14" @default.
• W2085963223 title "An approach to the calibrationless determination of copper and lead by anodic stripping voltammetry at thin mercury film microelectrodes. Application to well water and rain" @default.
• W2085963223 cites W10779080 @default.
• W2085963223 cites W1510149286 @default.
• W2085963223 cites W1542090321 @default.
• W2085963223 cites W1570421372 @default.
• W2085963223 cites W1968975304 @default.
• W2085963223 cites W1970547067 @default.
• W2085963223 cites W2009965540 @default.
• W2085963223 cites W2013346596 @default.
• W2085963223 cites W2015350049 @default.
• W2085963223 cites W2016235483 @default.
• W2085963223 cites W2018090003 @default.
• W2085963223 cites W2020788602 @default.
• W2085963223 cites W2021748302 @default.
• W2085963223 cites W2028896712 @default.
• W2085963223 cites W2029746872 @default.
• W2085963223 cites W2030190411 @default.
• W2085963223 cites W2030808360 @default.
• W2085963223 cites W2036557798 @default.
• W2085963223 cites W2039921840 @default.
• W2085963223 cites W2040765894 @default.
• W2085963223 cites W2046036348 @default.
• W2085963223 cites W2048851469 @default.
• W2085963223 cites W2060528125 @default.
• W2085963223 cites W2071492842 @default.
• W2085963223 cites W2073540943 @default.
• W2085963223 cites W2078451556 @default.
• W2085963223 cites W2080707684 @default.
• W2085963223 cites W2083882605 @default.
• W2085963223 cites W2086101390 @default.
• W2085963223 cites W2094440467 @default.
• W2085963223 cites W2119728241 @default.
• W2085963223 cites W2131011481 @default.
• W2085963223 cites W2146981257 @default.
• W2085963223 cites W2147494207 @default.
• W2085963223 cites W2155498985 @default.
• W2085963223 cites W2334652445 @default.
• W2085963223 cites W2417367996 @default.
• W2085963223 doi "https://doi.org/10.1016/s0003-2670(97)00114-1" @default.
• W2085963223 hasPublicationYear "1997" @default.
• W2085963223 type Work @default.
• W2085963223 sameAs 2085963223 @default.
• W2085963223 citedByCount "21" @default.
• W2085963223 countsByYear W20859632232012 @default.
• W2085963223 countsByYear W20859632232014 @default.
• W2085963223 countsByYear W20859632232015 @default.
• W2085963223 countsByYear W20859632232017 @default.
• W2085963223 countsByYear W20859632232023 @default.
• W2085963223 crossrefType "journal-article" @default.
• W2085963223 hasAuthorship W2085963223A5000158309 @default.
• W2085963223 hasAuthorship W2085963223A5069536623 @default.
• W2085963223 hasAuthorship W2085963223A5077034519 @default.
• W2085963223 hasConcept C111670793 @default.
• W2085963223 hasConcept C113196181 @default.
• W2085963223 hasConcept C119128265 @default.
• W2085963223 hasConcept C145148216 @default.
• W2085963223 hasConcept C147789679 @default.
• W2085963223 hasConcept C17525397 @default.
• W2085963223 hasConcept C178790620 @default.
• W2085963223 hasConcept C184651966 @default.
• W2085963223 hasConcept C185592680 @default.
• W2085963223 hasConcept C187428577 @default.
• W2085963223 hasConcept C199360897 @default.
• W2085963223 hasConcept C2182769 @default.
• W2085963223 hasConcept C23531484 @default.
• W2085963223 hasConcept C2777777548 @default.
• W2085963223 hasConcept C2778695967 @default.
• W2085963223 hasConcept C2779896888 @default.
• W2085963223 hasConcept C41008148 @default.
• W2085963223 hasConcept C43617362 @default.
• W2085963223 hasConcept C52859227 @default.
• W2085963223 hasConcept C544778455 @default.
• W2085963223 hasConcept C68801617 @default.
• W2085963223 hasConcept C81557720 @default.
• W2085963223 hasConcept C89395315 @default.
• W2085963223 hasConceptScore W2085963223C111670793 @default.
• W2085963223 hasConceptScore W2085963223C113196181 @default.
• W2085963223 hasConceptScore W2085963223C119128265 @default.
• W2085963223 hasConceptScore W2085963223C145148216 @default.
• W2085963223 hasConceptScore W2085963223C147789679 @default.
• W2085963223 hasConceptScore W2085963223C17525397 @default.
• W2085963223 hasConceptScore W2085963223C178790620 @default.
• W2085963223 hasConceptScore W2085963223C184651966 @default.
• W2085963223 hasConceptScore W2085963223C185592680 @default.
• W2085963223 hasConceptScore W2085963223C187428577 @default.
• W2085963223 hasConceptScore W2085963223C199360897 @default.
• W2085963223 hasConceptScore W2085963223C2182769 @default.
• W2085963223 hasConceptScore W2085963223C23531484 @default.
• W2085963223 hasConceptScore W2085963223C2777777548 @default.
• W2085963223 hasConceptScore W2085963223C2778695967 @default.
• W2085963223 hasConceptScore W2085963223C2779896888 @default.

• next