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- W2085981844 abstract "The bis(germyl)platinum complex [Pt(GeHPh2)2(dmpe)] (1) (dmpe = 1,2-bis(dimethylphosphino)ethane) reacts with a small excess of H2GePh2 at 90 °C to produce four-membered germaplatinacycle [Pt(GePh2GePh2GePh2)(dmpe)] (2). Further reaction of 2 with excess H2GePh2 at 90 °C forms tetragermaplatinacyclopentane [Pt(GePh2GePh2GePh2GePh2)(dmpe)] (3), while 3 is obtained also by the direct reaction of excess H2GePh2 with 1 for a prolonged period. Complexes 1−3 were characterized by X-ray crystallography and NMR spectroscopy. Germaplatinacycles 2 and 3 react with H3GePh to cause cleavage of the Pt−Ge bonds and formation of the oligogermanes H(GePh2)3H and H(GePh2)4H, respectively." @default.
- W2085981844 created "2016-06-24" @default.
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- W2085981844 date "2009-09-25" @default.
- W2085981844 modified "2023-10-18" @default.
- W2085981844 title "Formation and Ring Expansion of Germaplatinacycles via Dehydrogenative Ge−Ge and Ge−Pt Bond-Forming Reactions" @default.
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- W2085981844 doi "https://doi.org/10.1021/om900505k" @default.
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