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• W2085983497 abstract "The 13C NMR spectra of methyl alpha- and beta-D-galactopyranosides, and methyl alpha- and beta-D-glucopyranosides were recorded and show that the Delta(deltaC-4) values for methyl alpha- and beta-D-galactopyranosides increase most rapidly, whereas those for methyl alpha- and beta-D-glucopyranosides vary hardly with increasing molality of calcium nitrate. It can be concluded that ax-OH-4 interacts more strongly with Ca2+ than eq-OH-4 group, namely, the Ca2+ ion interaction with ax-OH-4 leads to a stronger deshielding of the C-4 atom. Compared with other C atoms, the chemical shifts of both C-1 and C-5 atoms in these two types of glycosides decrease relatively rapidly as molality of calcium nitrate increases, indicating that the nitrate ion attractions for these glycosides cause a relatively strong enhancing shielding effect of C-1 and C-5 atoms." @default.
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• W2085983497 date "2008-11-01" @default.
• W2085983497 modified "2023-10-14" @default.
• W2085983497 title "Interactions of calcium nitrate with pyranosides in water: A 13C NMR study" @default.
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• W2085983497 doi "https://doi.org/10.1016/j.saa.2007.11.015" @default.
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