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• W2085984429 abstract "The HeI photoelectron spectra of the Ph2ESiMe3 (E = N, P, As, and Sb) derivatives have been assigned with the aid of those of related simpler molecules. The substitution of a trimethylsilyl group for a hydrogen atom in Ph2EH to give the title compounds results in a significant reduction of the lone pair ionization energy of the fifth group atom when E ≠ N. When E = N, a slight stabilization is observed. This behaviour is probably attributable to the fact that the structure around the nitrogen atom is much further from planarity in the silyl derivative than in Ph2NH." @default.
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• W2085984429 date "1988-01-01" @default.
• W2085984429 modified "2023-10-11" @default.
• W2085984429 title "Ultraviolet photoelectron spectroscopy of diphenyltrimethylsilyl-amine, -phosphine, -arsine, and -stibine" @default.
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• W2085984429 doi "https://doi.org/10.1016/0022-328x(88)80500-x" @default.
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