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• W2085987767 abstract "Ultrananocrystalline diamond/amorphous carbon nanocomposite films (UNCD/a-C) have been deposited by microwave plasma chemical vapour deposition at 600 °C from 17% CH4/N2 mixtures. The as-grown films turned out to be hydrogen terminated and very stable. Photochemical amination of H-terminated diamond is a well-established route to attach functional groups to such surfaces for applications in biosensors. Here we report on experiments to aminate UNCD surfaces directly by exposure to ammonia plasmas. Thereafter the surfaces were reacted with the heterobifunctional crosslinker molecule SSMCC bearing a N-hydroxysuccinimide (NHS) ester group which should react with the surface NH2 groups. By means of X-ray photoelectron spectroscopy (XPS), contact angle measurements and fluorescence microscopy it is shown that both steps, plasma amination and SSMCC attachment lead to the desired aims. On the other hand, experiments to attach a thiol-bearing fluorescein molecule directly to H-terminated UNCD films turned out to be partially successful although according to literature such a reaction should be very unlikely." @default.
• W2085987767 created "2016-06-24" @default.
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• W2085987767 date "2011-02-01" @default.
• W2085987767 modified "2023-10-06" @default.
• W2085987767 title "Plasma amination of ultrananocrystalline diamond/amorphous carbon composite films for the attachment of biomolecules" @default.
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• W2085987767 doi "https://doi.org/10.1016/j.diamond.2010.12.010" @default.
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