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- W2085990531 abstract "The reactivities (composition curves) found during the copolymerization of ethylene, as well as the copolymer densitities as a function of composition, have been used to divide the CH2=CHPO(OR)2 (M2) monomers into 2 groups: 1) R=C6H5 and C2H4Cl and 2) R=C4H9 and iso-C4H9. This correlates well with the polarity differences of M2. The first group is characterized by higher reactivities, especially when the M2 content in the reaction mixture is high. The rapid drop of the reaction rate and of the mol. wt. of the copolymers, when the M2 content is increased in the reaction mixture, and the relatively large rate of the M2 homopolymerization, can be explained by the competition of the two mechanisms of chain transfer. An intramolecular reaction is dominant at the start and yields an intermediate P∗ radical. Chain transfer is faster at a larger M2 content and hydrogen will dissociate from R." @default.
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- W2085990531 date "1976-01-01" @default.
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- W2085990531 title "Radical copolymerization of ethylene with vinyl phosphonates under pressure" @default.
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- W2085990531 doi "https://doi.org/10.1016/0032-3950(76)90486-x" @default.
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