Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085993978> ?p ?o ?g. }
- W2085993978 abstract "A thermodynamic scaling law for the relaxation times of complex liquids as a function of temperature and volume has been proposed in the literature: τ(T,V) = ƒ(TVγ), where γ is a material-dependent constant. We test this scaling for six materials, linear polystyrene, star polystyrene, two polycyanurate networks, poly(vinyl acetate), and poly(vinyl chloride), and compare the thermodynamic scaling to T – Tg scaling, where τ = ƒ(T – Tg). The thermodynamic scaling law successfully reduces the data for all of the samples; however, polymers with similar structures but different glass transition (Tg) and pressure-volume-temperature (PVT) behavior, i.e., the two polycyanurates, cannot be superposed unless the scaling law is normalized by TgVgγ. On the other hand, the T – Tg scaling successfully reduced data for all polymers, including those having similar microstructures. In addition, the T – Tg scaling is easier to implement since it does not require knowledge of the PVT behavior of the material. The relationship between TgVgγ/TVγ and T – Tg scaling is clarified and is found to be weakly dependent on pressure." @default.
- W2085993978 created "2016-06-24" @default.
- W2085993978 creator A5034830121 @default.
- W2085993978 creator A5042982285 @default.
- W2085993978 date "2011-08-18" @default.
- W2085993978 modified "2023-10-17" @default.
- W2085993978 title "Thermodynamic scaling of polymer dynamics versus T – Tg scaling" @default.
- W2085993978 cites W1554007067 @default.
- W2085993978 cites W1944915281 @default.
- W2085993978 cites W1966943272 @default.
- W2085993978 cites W1967303178 @default.
- W2085993978 cites W1982421189 @default.
- W2085993978 cites W1984519826 @default.
- W2085993978 cites W1985862472 @default.
- W2085993978 cites W1987666485 @default.
- W2085993978 cites W1988100940 @default.
- W2085993978 cites W1988163775 @default.
- W2085993978 cites W1990469406 @default.
- W2085993978 cites W1990873702 @default.
- W2085993978 cites W1992306930 @default.
- W2085993978 cites W1996016803 @default.
- W2085993978 cites W1998973061 @default.
- W2085993978 cites W2001149062 @default.
- W2085993978 cites W2001538002 @default.
- W2085993978 cites W2011835094 @default.
- W2085993978 cites W2013313194 @default.
- W2085993978 cites W2015586919 @default.
- W2085993978 cites W2018249864 @default.
- W2085993978 cites W2018543903 @default.
- W2085993978 cites W2041935412 @default.
- W2085993978 cites W2042645663 @default.
- W2085993978 cites W2042854565 @default.
- W2085993978 cites W2046755679 @default.
- W2085993978 cites W2049821737 @default.
- W2085993978 cites W2049923854 @default.
- W2085993978 cites W2050624435 @default.
- W2085993978 cites W2052142375 @default.
- W2085993978 cites W2055611713 @default.
- W2085993978 cites W2060909999 @default.
- W2085993978 cites W2062396625 @default.
- W2085993978 cites W2069364236 @default.
- W2085993978 cites W2070334848 @default.
- W2085993978 cites W2070998624 @default.
- W2085993978 cites W2071785970 @default.
- W2085993978 cites W2074723317 @default.
- W2085993978 cites W2090627946 @default.
- W2085993978 cites W2102807769 @default.
- W2085993978 cites W2111185654 @default.
- W2085993978 cites W2114020139 @default.
- W2085993978 cites W2146613191 @default.
- W2085993978 cites W2156370397 @default.
- W2085993978 cites W2593554485 @default.
- W2085993978 cites W3099225940 @default.
- W2085993978 doi "https://doi.org/10.1063/1.3624903" @default.
- W2085993978 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21861582" @default.
- W2085993978 hasPublicationYear "2011" @default.
- W2085993978 type Work @default.
- W2085993978 sameAs 2085993978 @default.
- W2085993978 citedByCount "22" @default.
- W2085993978 countsByYear W20859939782012 @default.
- W2085993978 countsByYear W20859939782015 @default.
- W2085993978 countsByYear W20859939782016 @default.
- W2085993978 countsByYear W20859939782017 @default.
- W2085993978 countsByYear W20859939782018 @default.
- W2085993978 countsByYear W20859939782020 @default.
- W2085993978 countsByYear W20859939782021 @default.
- W2085993978 countsByYear W20859939782022 @default.
- W2085993978 crossrefType "journal-article" @default.
- W2085993978 hasAuthorship W2085993978A5034830121 @default.
- W2085993978 hasAuthorship W2085993978A5042982285 @default.
- W2085993978 hasConcept C121332964 @default.
- W2085993978 hasConcept C122865956 @default.
- W2085993978 hasConcept C15744967 @default.
- W2085993978 hasConcept C159985019 @default.
- W2085993978 hasConcept C188027245 @default.
- W2085993978 hasConcept C192562407 @default.
- W2085993978 hasConcept C20556612 @default.
- W2085993978 hasConcept C2524010 @default.
- W2085993978 hasConcept C2776029896 @default.
- W2085993978 hasConcept C2777922577 @default.
- W2085993978 hasConcept C2988430800 @default.
- W2085993978 hasConcept C33923547 @default.
- W2085993978 hasConcept C521977710 @default.
- W2085993978 hasConcept C77805123 @default.
- W2085993978 hasConcept C97355855 @default.
- W2085993978 hasConcept C99844830 @default.
- W2085993978 hasConceptScore W2085993978C121332964 @default.
- W2085993978 hasConceptScore W2085993978C122865956 @default.
- W2085993978 hasConceptScore W2085993978C15744967 @default.
- W2085993978 hasConceptScore W2085993978C159985019 @default.
- W2085993978 hasConceptScore W2085993978C188027245 @default.
- W2085993978 hasConceptScore W2085993978C192562407 @default.
- W2085993978 hasConceptScore W2085993978C20556612 @default.
- W2085993978 hasConceptScore W2085993978C2524010 @default.
- W2085993978 hasConceptScore W2085993978C2776029896 @default.
- W2085993978 hasConceptScore W2085993978C2777922577 @default.
- W2085993978 hasConceptScore W2085993978C2988430800 @default.
- W2085993978 hasConceptScore W2085993978C33923547 @default.
- W2085993978 hasConceptScore W2085993978C521977710 @default.
- W2085993978 hasConceptScore W2085993978C77805123 @default.