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- W2086004896 abstract "The carbon shielding anisotropies of CCl3F and CCl3CF3 have been determined from analyses of natural abundance carbon-13 spectra in partially ordered nematic liquid-crystal solutions. The results for σ| − σ⊥ are: CCl3F, 29 ± 8 ppm; CCl3CF3 − CCl3 carbon, −14 ± 12 ppm; CF3 carbon, −12 ± 12 ppm. Complete shielding tensors were obtained for the systems CCl3X, X = H, F, Cl, and CF3. It was found that σ| remained constant for each of these molecules, whereas σ|d, evaluated using the atom-dipole method, is constant for CCl3H, CCl3F, and CCl4, but changes appreciably for CCl3CF3 due to the presence of fluorine atoms lying off the symmetry axis. The shielding trends for the CCl3X series were compared to the CH3X series, for which extensive experimental and theoretical data exist. The two series were found to exhibit similar behaviour in all aspects considered. The spin-rotation constants were evaluated for the CCl3X molecules." @default.
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- W2086004896 date "1976-05-01" @default.
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- W2086004896 title "Carbon-13 shielding tensors of CCl3X systems from studies of liquid-crystal solutions" @default.
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- W2086004896 doi "https://doi.org/10.1016/0022-2364(76)90311-5" @default.
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