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- W2086010160 abstract "Two depsipeptide metabolites, scyptolin A and B, were reported recently from the axenically grown terrestrial cyanobacterium Scytonema hofmanni PCC 7110. A related, novel depsipeptide was isolated from this Scytonema and designated hofmannolin. The amino acid analysis in context with infrared, mass and 1H/13C-NMR spectroscopies revealed a cyclic depsipeptide structure of M(r) 1073 belonging to the class of cyanopeptolins. Two peculiar features distinguish hofmannolin from other cyanopeptolins: O-methylated tyrosine forms the sixth moiety from the amino terminus, and the N-terminus is blocked by 2-hydroxy-3-methyl-valeric acid, a residue that has not yet been reported as a component in other cyanopeptolins. Preliminary assays of peptidase inhibitory and antimicrobial activities suggested negligible bioactivities for hofmannolin." @default.
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- W2086010160 date "2003-11-01" @default.
- W2086010160 modified "2023-10-06" @default.
- W2086010160 title "Hofmannolin, a cyanopeptolin from Scytonema hofmanni PCC 7110" @default.
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- W2086010160 doi "https://doi.org/10.1016/s0031-9422(03)00467-9" @default.
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