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- W2086041572 abstract "Enthalpy increment measurements on CeTe2O6 (s) and ThTe2O6 (s) were carried out using a Calvet micro-calorimeter. The enthalpy increment values were least squares analyzed, with the constraint that H0(T)−H0 (298.15 K) at 298.15 equals 0 and Cp0 (298.15 K) is equal to the value estimated by Kellog’s method. The dependence of the enthalpy increment with temperature can be given as:H0(T)−H0 (298.15 K)(J mol−1)=189.95 T (K)+15.226×10−3 T2 (K) +15.414×105/T (K)−63157 (CeTe2O6 (s), 391.5–848.0 K)H0(T)−H0 (298.15 K)(J mol−1)=191.34 T (K)+14.993×10−3 T2 (K) +14.668×105/T (K)−63300 (ThTe2O6 (s), 391.5–909.3 K) Molar heat capacity Cp0(T), S(T) and Gibb’s free energy functions were evaluated." @default.
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- W2086041572 date "1999-08-01" @default.
- W2086041572 modified "2023-09-23" @default.
- W2086041572 title "Thermal properties of cerium and thorium tellurates" @default.
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- W2086041572 doi "https://doi.org/10.1016/s0925-8388(99)00181-4" @default.
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