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- W2086042849 abstract "Abstract In a binary liquid alloy, regular solution theory leads to the concentration fluctuations 〈(Δc)2〉 as where w is the interchange energy in the theory. It is pointed out that Miedema's work gives an explicit expression for w in an AB alloy in terms of a) the boundary densities ρA and ρB in pure metals A and B and b) the electronegativity difference (xA—xB ). Since w has been been estimated both from thermodynamic data and from phase diagrams, a link is thereby forged between the chemical theory of solutions embodied in Eq. (i) and the electron theory of metals. Some numerical consequences for the interchange energy w are explored briefly for mixtures of two alkali metals. It is finally stressed that the type of theory based on Eq. (i) is not applicable when size differences become large." @default.
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- W2086042849 date "1981-11-01" @default.
- W2086042849 modified "2023-10-14" @default.
- W2086042849 title "Relation of Regular Solution Theory of Liquid Metal Alloys to Miedema's Work" @default.
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- W2086042849 doi "https://doi.org/10.1080/00319108108079105" @default.
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