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- W2086057681 abstract "A mechanism for the influence of doping on the electron spectrum Nd2−xCexCuO4 and Ba1−xKxBiO3 is proposed. In the framework of simple model taking into account the local nature of HTSC electronic properties the mechanism of formation of “negative-U centers” (with the pair orbital placed at the top of the oxygen subband) is considered. The nature of interelectron attraction on oxygen-U-centers is the dependence of Cu1+-state energy on the charge state of nearest O-atom. In turns out that the energy of Cu1+-state for copper atom nearest to O−ion is higher than one for copper atom nearest to O2- and O0 ions." @default.
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- W2086057681 date "1994-12-01" @default.
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- W2086057681 title "The formation of negative-U centers in doped HTSC" @default.
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- W2086057681 doi "https://doi.org/10.1016/0921-4534(94)92378-7" @default.
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