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- W2086093567 abstract "Abstract The synthesis of the first example of a [1,4]diazepino[2,3- c ]isoxazole derivative is reported. Reaction of an imidazo[4,5- c ]isoxazole with acetylenic esters has been shown to lead to the formation of 2-pyrrol-2-yl imidazoles. Here we report an alternative reaction pathway in which the fused imidazole ring adds a molecule of acetylenic ester, and undergoes ring expansion to a fused [1,4]diazepine. A mechanism for the reaction is discussed." @default.
- W2086093567 created "2016-06-24" @default.
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- W2086093567 date "2000-11-01" @default.
- W2086093567 modified "2023-09-26" @default.
- W2086093567 title "Reactions of an imidazo[4,5-c]isoxazole-6-carboxylate with dimethyl acetylenedicarboxylate; formation of the first example of a [1,4]diazepino[2,3-c]isoxazole" @default.
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- W2086093567 doi "https://doi.org/10.1016/s0040-4039(00)01682-8" @default.
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