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• W2086108659 abstract "The reaction rate constants for halogen abstraction of Ph3Sn· and Ph3Si· have been determined by xenon-flash photolysis method. The absolute rate constants for the reactivity of Ph3Sn· with several alkyl halides have been compared with the relative ones; the agreement between the both methods was fairly good. For Ph3Sn·, the rate constant (in unit of mol−1 dm3 s−1) of n-BuCl (5.2×102) was smaller than that of n-BuBr (3.1×106) by a factor of ca. 1⁄104. With changing the alkyl halides, the rate constants for Ph3Si· and Ph3Sn· varied similarly, although the rate constants for Ph3Si· were larger than those for Ph3Sn· by factors of 50–100. The reactivity of alkyl halides increased with a decrease in the bond-dissociation energy of the R–X (X=Cl, Br)." @default.
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• W2086108659 date "1991-03-01" @default.
• W2086108659 modified "2023-10-12" @default.
• W2086108659 title "Flash Photolysis Study for Halogen Abstraction of and Ph₃Sn· and Ph₃Si· from Alkyl Halides" @default.
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• W2086108659 doi "https://doi.org/10.1246/bcsj.64.962" @default.
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