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- W2086132324 abstract "A study was made of compound formation in the systems EuMoO and EuWO with the objective of preparing the Eu2+ analogues of the known Sr2+ compounds EuMoO4, EuWO4 and EuMoO3. The scheelite-type compounds EuMoO4 and EuWO4 were easily prepared. No EuMoO3 compound could be prepared over the temperature range 1200° – 1400°C. In the course of the study three new compounds containing trivalent rare earths were encountered, Eu2Mo2O7, Sm2Mo2O7 and Eu6WO12. The first two have cubic pyrochlore-type structures while Eu6WO12 has a defect cubic fluorite structure. The necessity of considering thermodynamic parameters as well as size, charge and polarizability in systematic crystal chemistry is discussed." @default.
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- W2086132324 date "1971-01-01" @default.
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- W2086132324 title "Divalent europium compounds in the systems EuMoO and EuWO" @default.
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- W2086132324 doi "https://doi.org/10.1016/0025-5408(71)90156-5" @default.
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