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- W2086139147 abstract "Molybdates such as CaMoO4 and SrMoO4 have received much attention recently because of their interesting luminescence and structural properties. Herein, we report a microemulsion-mediated method as a novel technique to synthesize CaMoO4 and SrMoO4 mesocrystals with high hierarchy and with hollow structure. The “arms” of the flowerlike 3D mesocrystals are radial and are about 2−3 μm in length. They are constructed from nanoparticles with regular morphology and a size of about 150−300 nm. Study on the formation mechanism of the superstructures reveals that the oriented aggregation mechanism is responsible for the self-assembly. The mesocrystals of CaMoO4 and SrMoO4 are shown to be in a thermodynamically metastable state, which can be destroyed by further reaction time or temperature change." @default.
- W2086139147 created "2016-06-24" @default.
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- W2086139147 date "2006-06-29" @default.
- W2086139147 modified "2023-10-14" @default.
- W2086139147 title "Large-Scale Fabrication of Novel Hierarchical 3D CaMoO<sub>4</sub> and SrMoO<sub>4</sub> Mesocrystals via a Microemulsion-Mediated Route" @default.
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- W2086139147 doi "https://doi.org/10.1021/cg060133h" @default.
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