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- W2086148981 abstract "2-Substituted-2,7,9-decatrienoates undergo an iron-catalyzed carbocyclization to yield trans-disubstituted cyclopentanes in moderate-to-good chemical yields. The cyclization products are formally the result of a [4+4]-ene reaction in which cis-propenyl and 2-acroyl functionalities are introduced as appendages to the newly formed cyclopentane ring by the cyclization. Triene ester substrates bearing an alkyl substituent at the 4- or 6-positions cyclize with high 1,2-stereoinduction to yield trisubstituted cyclopentanes in which the relative stereochemistry between three contiguous stereocenters is controlled." @default.
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- W2086148981 date "1990-01-01" @default.
- W2086148981 modified "2023-09-27" @default.
- W2086148981 title "Catalytic iron-mediated ene carbocyclizations: formal [4+4]-ene reactions of triene esters" @default.
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- W2086148981 doi "https://doi.org/10.1016/s0040-4020(01)87749-8" @default.
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