Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086150430> ?p ?o ?g. }
- W2086150430 endingPage "2769" @default.
- W2086150430 startingPage "2757" @default.
- W2086150430 abstract "The syntheses of trifluoromethanesulphonato (OTf) complexes of CoII, NiII, CuII, FeIII and GaIII by the reaction of simple metal salts (Cl−, Br−, CO32−, ClO4− or metallic gallium with trifluoromethanesulphonic acid have been systematically investigated. Comparison of the vibrational spectra of coordinated OTf in these complexes with that in simple ionic salts indicates the ligand to be bridging bidentate in M(OTf)3, M = Ga, Fe and in M(OTf)2, M = Cu and bridging tridentate in M′(OTf)2, M′= Co, Ni, Cd. EXAFS spectroscopic data can be interpreted in terms of layered structural arrangements for Co, Ni, Cd and Ga trifluoromethanesulphonato complexes, similar to that of the corresponding anhydrous metal perchlorates studied previously. In Cu(OTf)2, however, the copper atom is in a square planar environment. The short metal-oxygen distances, 1.96–2.09 Å are consistent with strong interactions between the ligand and metallic centre." @default.
- W2086150430 created "2016-06-24" @default.
- W2086150430 creator A5002635325 @default.
- W2086150430 creator A5010492405 @default.
- W2086150430 creator A5019663602 @default.
- W2086150430 creator A5047940492 @default.
- W2086150430 creator A5073537711 @default.
- W2086150430 creator A5077521407 @default.
- W2086150430 date "1991-01-01" @default.
- W2086150430 modified "2023-09-25" @default.
- W2086150430 title "Synthesis, vibrational spectroscopy and EXAFS analysis of some divalent and trivalent trifluoromethanesulphonato complexes" @default.
- W2086150430 cites W1609923210 @default.
- W2086150430 cites W1856557506 @default.
- W2086150430 cites W1980615022 @default.
- W2086150430 cites W1990147235 @default.
- W2086150430 cites W1990797763 @default.
- W2086150430 cites W2007017421 @default.
- W2086150430 cites W2008401499 @default.
- W2086150430 cites W2019228232 @default.
- W2086150430 cites W2021180276 @default.
- W2086150430 cites W2028344041 @default.
- W2086150430 cites W2037246952 @default.
- W2086150430 cites W2054864406 @default.
- W2086150430 cites W2060719803 @default.
- W2086150430 cites W2065466753 @default.
- W2086150430 cites W2068197043 @default.
- W2086150430 cites W2072958106 @default.
- W2086150430 cites W2073026671 @default.
- W2086150430 cites W2076147196 @default.
- W2086150430 cites W2081936026 @default.
- W2086150430 cites W2084373131 @default.
- W2086150430 cites W2088126112 @default.
- W2086150430 cites W2088249985 @default.
- W2086150430 cites W2089678791 @default.
- W2086150430 cites W2090304058 @default.
- W2086150430 cites W2129681109 @default.
- W2086150430 cites W2150246017 @default.
- W2086150430 cites W2330700662 @default.
- W2086150430 cites W2369004914 @default.
- W2086150430 cites W2622584111 @default.
- W2086150430 cites W2950867946 @default.
- W2086150430 cites W2951421843 @default.
- W2086150430 cites W3137891055 @default.
- W2086150430 cites W4247272669 @default.
- W2086150430 cites W4255577684 @default.
- W2086150430 doi "https://doi.org/10.1016/s0277-5387(00)86177-x" @default.
- W2086150430 hasPublicationYear "1991" @default.
- W2086150430 type Work @default.
- W2086150430 sameAs 2086150430 @default.
- W2086150430 citedByCount "35" @default.
- W2086150430 countsByYear W20861504302013 @default.
- W2086150430 countsByYear W20861504302014 @default.
- W2086150430 countsByYear W20861504302017 @default.
- W2086150430 countsByYear W20861504302018 @default.
- W2086150430 countsByYear W20861504302020 @default.
- W2086150430 countsByYear W20861504302021 @default.
- W2086150430 countsByYear W20861504302022 @default.
- W2086150430 crossrefType "journal-article" @default.
- W2086150430 hasAuthorship W2086150430A5002635325 @default.
- W2086150430 hasAuthorship W2086150430A5010492405 @default.
- W2086150430 hasAuthorship W2086150430A5019663602 @default.
- W2086150430 hasAuthorship W2086150430A5047940492 @default.
- W2086150430 hasAuthorship W2086150430A5073537711 @default.
- W2086150430 hasAuthorship W2086150430A5077521407 @default.
- W2086150430 hasConcept C107861141 @default.
- W2086150430 hasConcept C115624301 @default.
- W2086150430 hasConcept C119824511 @default.
- W2086150430 hasConcept C121332964 @default.
- W2086150430 hasConcept C145148216 @default.
- W2086150430 hasConcept C153642686 @default.
- W2086150430 hasConcept C178516000 @default.
- W2086150430 hasConcept C178790620 @default.
- W2086150430 hasConcept C179104552 @default.
- W2086150430 hasConcept C185592680 @default.
- W2086150430 hasConcept C2182769 @default.
- W2086150430 hasConcept C544153396 @default.
- W2086150430 hasConcept C544778455 @default.
- W2086150430 hasConcept C62520636 @default.
- W2086150430 hasConcept C8010536 @default.
- W2086150430 hasConceptScore W2086150430C107861141 @default.
- W2086150430 hasConceptScore W2086150430C115624301 @default.
- W2086150430 hasConceptScore W2086150430C119824511 @default.
- W2086150430 hasConceptScore W2086150430C121332964 @default.
- W2086150430 hasConceptScore W2086150430C145148216 @default.
- W2086150430 hasConceptScore W2086150430C153642686 @default.
- W2086150430 hasConceptScore W2086150430C178516000 @default.
- W2086150430 hasConceptScore W2086150430C178790620 @default.
- W2086150430 hasConceptScore W2086150430C179104552 @default.
- W2086150430 hasConceptScore W2086150430C185592680 @default.
- W2086150430 hasConceptScore W2086150430C2182769 @default.
- W2086150430 hasConceptScore W2086150430C544153396 @default.
- W2086150430 hasConceptScore W2086150430C544778455 @default.
- W2086150430 hasConceptScore W2086150430C62520636 @default.
- W2086150430 hasConceptScore W2086150430C8010536 @default.
- W2086150430 hasIssue "23-24" @default.
- W2086150430 hasLocation W20861504301 @default.
- W2086150430 hasOpenAccess W2086150430 @default.
- W2086150430 hasPrimaryLocation W20861504301 @default.