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- W2086190268 abstract "In the present article, a one-pot capping method with very simple procedure was developed to synthesize highly luminescent CdTe/CdS/ZnS quantum dots (QDs). CdTe aqueous solution was introduced into a precursor solution containing Cd2+, Zn2+ and mercaptopropionic acid (MPA), and sulfur solution was then added for capping a CdS/ZnS shell on CdTe core. Synthesis conditions such as refluxing time, dropping rate of Na2S and molar ratio of Cd2+:Zn2+:S2−:MPA were investigated. The optical properties of the as-prepared QDs in absoption and photoluminescence were studied. The experimental results revealed that the CdTe/CdS/ZnS QDs prepared by the one-pot capping method had photoluminescent quantum yield up to 73%, broad excitation spectrum of 100 nm, good pH tolerance and photostability. Transmission electron microscopy showed that the CdTe/CdS/ZnS QDs were nearly spherical and monodispersed with the average size of about 10 nm. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy confirmed the core/shell/shell structure of CdTe/CdS/ZnS. XRD demonstrated that the CdTe/CdS/ZnS QDs possessed ideal crystal structure." @default.
- W2086190268 created "2016-06-24" @default.
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- W2086190268 date "2013-06-01" @default.
- W2086190268 modified "2023-10-12" @default.
- W2086190268 title "Synthesis of highly luminescent CdTe/CdS/ZnS quantum dots by a one-pot capping method" @default.
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- W2086190268 doi "https://doi.org/10.1016/j.cej.2013.04.027" @default.
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