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- W2086201312 endingPage "9540" @default.
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- W2086201312 abstract "Diazoalkanes regiospecifically react with dimethyl 1-(formylamino)ethylenephosphonate (1a) to afford 5-substituted dimethyl 3-(formylamino)-4,5-dihydro-3H-pyrazol-3-phosphonates 2 in high yields. Their thermal decomposition followed by hydrolysis provides a straightforward access to 2-substituted 1-aminocyclopropanephosphonic acids 4. Aromatization of 2 under acidic conditions leads to 3-phosphorylated pyrazoles 5." @default.
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- W2086201312 date "2011-12-01" @default.
- W2086201312 modified "2023-09-24" @default.
- W2086201312 title "1,3-Dipolar cycloaddition of diazoalkanes onto dimethyl 1-(formylamino)ethylenephosphonate: a new route to 1-aminocyclopropanephosphonic acids and 3-phosphorylated pyrazoles" @default.
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- W2086201312 doi "https://doi.org/10.1016/j.tet.2011.10.010" @default.
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