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- W2086214976 abstract "Reaction of CO with trans-Ir(CO)(Cl)(TPPTS)2 in DMSO and H2O give [Ir(CO)3(TPPTS)2]Cl (H2O and DMSO) and Ir(CO)2(Cl)(TPPTS)2 (DMSO only). In both solvents the carbonylation is reversed by passing N2 through the solution. In water, further reactions occur slowly, including water-gas-shift reactions and formation of Ir(CO)2(TPPTS)3+. This trisphosphine complex was independently prepared to examine its reactions. In DMSO, reaction with CO readily forms Ir(CO)3(TPPTS)2+; no reaction with CO is observed in water. Reaction of Ir(CO)2(TPPTS)3+ with H2 occurs through TPPTS dissociation giving Ir(CO)2(H)2(TPPTS)2+ initially before reaction with free TPPTS gives Ir(CO)(H)2(TPPTS)3+ as the final product. Hydrogen bonding from water to the sulfonated phosphine ligands provides a reasonable explanation for the differing ligand substitution behavior in DMSO and H2O." @default.
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- W2086214976 date "1997-12-01" @default.
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- W2086214976 title "Carbonylation of <i>trans</i>-Ir(CO)Cl(TPPTS)<sub>2</sub> and Reactivity of [Ir(CO)<sub>2</sub>(TPPTS)<sub>3</sub>]Cl (TPPTS = P(<i>m</i>-C<sub>6</sub>H<sub>4</sub>SO<sub>3</sub>Na)<sub>3</sub>) in DMSO and Water" @default.
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- W2086214976 doi "https://doi.org/10.1021/om970351v" @default.
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