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- W2086225616 abstract "The preparation of methyl (R)-o-chloromandelate via Ru-catalyzed asymmetric hydrogenation and transfer hydrogenation was investigated. With Ru-(R,R)-2,4,6-triisopropyl C6H2SO2-DPEN as the catalyst and HCOOH–Et3N azeotrope as the hydrogen donor, up to 92% ee was obtained in an optional condition. The synthesis of (S)-Clopidogrel was also studied." @default.
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- W2086225616 date "2009-06-01" @default.
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- W2086225616 title "Ru-catalyzed enantioselective preparation of methyl (R)-o-chloromandelate and its application in the synthesis of (S)-Clopidogrel" @default.
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- W2086225616 doi "https://doi.org/10.1016/j.jorganchem.2009.02.008" @default.
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