FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086230238> ?p ?o ?g. }

• W2086230238 endingPage "134" @default.
• W2086230238 startingPage "123" @default.
• W2086230238 abstract "Aerobic oxidation of mixtures of PrpepH (3), a peptide ligand that contains three of the five proposed donor centers of the metal-chelating portion of the antitumor drug bleomycin (BLM) and cobalt(II) salts (ratio 2:1) in water or methanol affords the cobalt(III) complex [Co(Prpep)2]+ which has been isolated as the perchlorate and the tetrafluoroborate salt. [Co(Prpep)2]C1O4·2.25H2O (5a) crystallizes in the orthorhombic space group Pbca with a=14.553- (5), b=16.765(7), c=21.745(8) Å and Z=8. The structure was refined to R=6.2% by using 3273 unique data (Fo2 > 2.5σ(Fo2)). The coordination geometry around low-spin Co(III) is octahedral with CoN(pyrimidine)=1.943(5), Co-N(imidazole)= 1.931(5) and Co-N(amido)=1.927(5) A, respectively. The complex is isolated as the mer isomer. On reduction, [Co(Prpep)2]+ yields a cobalt(II) species that rapidly decomposes in solution. The solution structure of [Co(Prpep)2]+ has been explored with the aid of one- and two-dimensional 1H and 13C NMR spectroscopy." @default.
• W2086230238 created "2016-06-24" @default.
• W2086230238 creator A5012021994 @default.
• W2086230238 creator A5043218984 @default.
• W2086230238 creator A5055868553 @default.
• W2086230238 creator A5060131715 @default.
• W2086230238 date "1989-06-01" @default.
• W2086230238 modified "2023-09-27" @default.
• W2086230238 title "Synthetic analogue approach to cobalt(III)-bleomycin: synthesis, crystal and solution structures and redox properties of bis(N-(2-(4-imidazolyl)ethyl)pyrimidine-4-carboxamido)cobalt(III) perchlorate·2.25H2O" @default.
• W2086230238 cites W1514044987 @default.
• W2086230238 cites W1515581375 @default.
• W2086230238 cites W1971765443 @default.
• W2086230238 cites W1975669045 @default.
• W2086230238 cites W1979940642 @default.
• W2086230238 cites W1980044104 @default.
• W2086230238 cites W1982905716 @default.
• W2086230238 cites W1984049509 @default.
• W2086230238 cites W1995991546 @default.
• W2086230238 cites W1999862280 @default.
• W2086230238 cites W2002727872 @default.
• W2086230238 cites W2005130670 @default.
• W2086230238 cites W2006571883 @default.
• W2086230238 cites W2007330769 @default.
• W2086230238 cites W2011800775 @default.
• W2086230238 cites W2014011471 @default.
• W2086230238 cites W2017982049 @default.
• W2086230238 cites W2021627410 @default.
• W2086230238 cites W2026726261 @default.
• W2086230238 cites W2030058267 @default.
• W2086230238 cites W2045239085 @default.
• W2086230238 cites W2046900004 @default.
• W2086230238 cites W2047773194 @default.
• W2086230238 cites W2048733939 @default.
• W2086230238 cites W2048810870 @default.
• W2086230238 cites W2048956886 @default.
• W2086230238 cites W2053522275 @default.
• W2086230238 cites W2054094681 @default.
• W2086230238 cites W2063005322 @default.
• W2086230238 cites W2068503305 @default.
• W2086230238 cites W2070458959 @default.
• W2086230238 cites W2072405958 @default.
• W2086230238 cites W2075249158 @default.
• W2086230238 cites W2083329060 @default.
• W2086230238 cites W2091299265 @default.
• W2086230238 cites W2092904871 @default.
• W2086230238 cites W2100099945 @default.
• W2086230238 cites W2136482827 @default.
• W2086230238 cites W2136958807 @default.
• W2086230238 cites W2317599232 @default.
• W2086230238 cites W3137851415 @default.
• W2086230238 cites W3137924943 @default.
• W2086230238 cites W4240843885 @default.
• W2086230238 cites W3024531262 @default.
• W2086230238 doi "https://doi.org/10.1016/s0020-1693(00)85412-2" @default.
• W2086230238 hasPublicationYear "1989" @default.
• W2086230238 type Work @default.
• W2086230238 sameAs 2086230238 @default.
• W2086230238 citedByCount "15" @default.
• W2086230238 crossrefType "journal-article" @default.
• W2086230238 hasAuthorship W2086230238A5012021994 @default.
• W2086230238 hasAuthorship W2086230238A5043218984 @default.
• W2086230238 hasAuthorship W2086230238A5055868553 @default.
• W2086230238 hasAuthorship W2086230238A5060131715 @default.
• W2086230238 hasConcept C115624301 @default.
• W2086230238 hasConcept C116569031 @default.
• W2086230238 hasConcept C145148216 @default.
• W2086230238 hasConcept C154881586 @default.
• W2086230238 hasConcept C155647269 @default.
• W2086230238 hasConcept C161790260 @default.
• W2086230238 hasConcept C170493617 @default.
• W2086230238 hasConcept C178790620 @default.
• W2086230238 hasConcept C179104552 @default.
• W2086230238 hasConcept C185592680 @default.
• W2086230238 hasConcept C198819137 @default.
• W2086230238 hasConcept C2779321679 @default.
• W2086230238 hasConcept C2780709120 @default.
• W2086230238 hasConcept C2780872544 @default.
• W2086230238 hasConcept C2780874372 @default.
• W2086230238 hasConcept C37243968 @default.
• W2086230238 hasConcept C39297587 @default.
• W2086230238 hasConcept C515602321 @default.
• W2086230238 hasConcept C55493867 @default.
• W2086230238 hasConcept C71240020 @default.
• W2086230238 hasConcept C8010536 @default.
• W2086230238 hasConceptScore W2086230238C115624301 @default.
• W2086230238 hasConceptScore W2086230238C116569031 @default.
• W2086230238 hasConceptScore W2086230238C145148216 @default.
• W2086230238 hasConceptScore W2086230238C154881586 @default.
• W2086230238 hasConceptScore W2086230238C155647269 @default.
• W2086230238 hasConceptScore W2086230238C161790260 @default.
• W2086230238 hasConceptScore W2086230238C170493617 @default.
• W2086230238 hasConceptScore W2086230238C178790620 @default.
• W2086230238 hasConceptScore W2086230238C179104552 @default.
• W2086230238 hasConceptScore W2086230238C185592680 @default.
• W2086230238 hasConceptScore W2086230238C198819137 @default.
• W2086230238 hasConceptScore W2086230238C2779321679 @default.
• W2086230238 hasConceptScore W2086230238C2780709120 @default.
• W2086230238 hasConceptScore W2086230238C2780872544 @default.

• next