Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086243399> ?p ?o ?g. }
- W2086243399 endingPage "84" @default.
- W2086243399 startingPage "75" @default.
- W2086243399 abstract "A series of WOx/ZrO2 with various tungsten loadings was prepared via incipient-wetness impregnation of zirconium hydroxide. The resulting thermally processed materials were characterised by XRD, XPS, porosimetry, NH3-TPD and pyridine FTIR spectroscopy to elucidate their composition, morphology and acidity, and subsequently tested in the esterification of palmitic acid with methanol. Catalytic performance was strongly dependent upon calcination temperature and W surface density. Esterification activity increased with increasing surface W density, reaching a maximum at 8.9 W nm−2 corresponding to near monolayer coverage. Subsequent growth of crystalline WO3 lowered activity, consistent with a decrease in the density of active surface sites. Calcination temperatures as high as 800 °C increased surface acidity and hence catalytic activity. The formation of polymeric tungstate species on zirconia is necessary to generate the Brönsted acid sites responsible for palmitic acid esterification under mild conditions." @default.
- W2086243399 created "2016-06-24" @default.
- W2086243399 creator A5031971765 @default.
- W2086243399 creator A5038843370 @default.
- W2086243399 creator A5060198588 @default.
- W2086243399 creator A5075327498 @default.
- W2086243399 date "2015-01-01" @default.
- W2086243399 modified "2023-09-26" @default.
- W2086243399 title "Physicochemical properties of WO x /ZrO 2 catalysts for palmitic acid esterification" @default.
- W2086243399 cites W103186430 @default.
- W2086243399 cites W189687435 @default.
- W2086243399 cites W1968768706 @default.
- W2086243399 cites W1972710229 @default.
- W2086243399 cites W1973197277 @default.
- W2086243399 cites W1977424248 @default.
- W2086243399 cites W1982430362 @default.
- W2086243399 cites W1987410635 @default.
- W2086243399 cites W1988169437 @default.
- W2086243399 cites W1989385514 @default.
- W2086243399 cites W1991027207 @default.
- W2086243399 cites W2007871362 @default.
- W2086243399 cites W2011102934 @default.
- W2086243399 cites W2011809778 @default.
- W2086243399 cites W2015161439 @default.
- W2086243399 cites W2016465968 @default.
- W2086243399 cites W2020871613 @default.
- W2086243399 cites W2022715607 @default.
- W2086243399 cites W2042359380 @default.
- W2086243399 cites W2045660731 @default.
- W2086243399 cites W2056749076 @default.
- W2086243399 cites W2062580620 @default.
- W2086243399 cites W2076528220 @default.
- W2086243399 cites W2077984406 @default.
- W2086243399 cites W2089691190 @default.
- W2086243399 cites W2090310105 @default.
- W2086243399 cites W2090749508 @default.
- W2086243399 cites W2124334175 @default.
- W2086243399 cites W2150326847 @default.
- W2086243399 cites W2155046778 @default.
- W2086243399 cites W2318655867 @default.
- W2086243399 cites W2328696867 @default.
- W2086243399 cites W2328722603 @default.
- W2086243399 cites W2952137902 @default.
- W2086243399 cites W3001177187 @default.
- W2086243399 doi "https://doi.org/10.1016/j.apcatb.2014.06.036" @default.
- W2086243399 hasPublicationYear "2015" @default.
- W2086243399 type Work @default.
- W2086243399 sameAs 2086243399 @default.
- W2086243399 citedByCount "71" @default.
- W2086243399 countsByYear W20862433992014 @default.
- W2086243399 countsByYear W20862433992015 @default.
- W2086243399 countsByYear W20862433992016 @default.
- W2086243399 countsByYear W20862433992017 @default.
- W2086243399 countsByYear W20862433992018 @default.
- W2086243399 countsByYear W20862433992019 @default.
- W2086243399 countsByYear W20862433992020 @default.
- W2086243399 countsByYear W20862433992021 @default.
- W2086243399 countsByYear W20862433992022 @default.
- W2086243399 countsByYear W20862433992023 @default.
- W2086243399 crossrefType "journal-article" @default.
- W2086243399 hasAuthorship W2086243399A5031971765 @default.
- W2086243399 hasAuthorship W2086243399A5038843370 @default.
- W2086243399 hasAuthorship W2086243399A5060198588 @default.
- W2086243399 hasAuthorship W2086243399A5075327498 @default.
- W2086243399 hasConcept C105569014 @default.
- W2086243399 hasConcept C114873805 @default.
- W2086243399 hasConcept C118792377 @default.
- W2086243399 hasConcept C123609680 @default.
- W2086243399 hasConcept C127413603 @default.
- W2086243399 hasConcept C134132462 @default.
- W2086243399 hasConcept C13965031 @default.
- W2086243399 hasConcept C160892712 @default.
- W2086243399 hasConcept C161790260 @default.
- W2086243399 hasConcept C178790620 @default.
- W2086243399 hasConcept C179104552 @default.
- W2086243399 hasConcept C185592680 @default.
- W2086243399 hasConcept C2777879272 @default.
- W2086243399 hasConcept C2778077586 @default.
- W2086243399 hasConcept C2778648569 @default.
- W2086243399 hasConcept C2779607525 @default.
- W2086243399 hasConcept C2779936771 @default.
- W2086243399 hasConcept C2780091686 @default.
- W2086243399 hasConcept C2781047139 @default.
- W2086243399 hasConcept C42360764 @default.
- W2086243399 hasConcept C534791751 @default.
- W2086243399 hasConcept C543025807 @default.
- W2086243399 hasConcept C6648577 @default.
- W2086243399 hasConcept C7082614 @default.
- W2086243399 hasConceptScore W2086243399C105569014 @default.
- W2086243399 hasConceptScore W2086243399C114873805 @default.
- W2086243399 hasConceptScore W2086243399C118792377 @default.
- W2086243399 hasConceptScore W2086243399C123609680 @default.
- W2086243399 hasConceptScore W2086243399C127413603 @default.
- W2086243399 hasConceptScore W2086243399C134132462 @default.
- W2086243399 hasConceptScore W2086243399C13965031 @default.
- W2086243399 hasConceptScore W2086243399C160892712 @default.
- W2086243399 hasConceptScore W2086243399C161790260 @default.
- W2086243399 hasConceptScore W2086243399C178790620 @default.