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• W2086247712 abstract "Site-specific average atomic concentrations computed for systems of Rh-Cu, Ni-Cu and Rh-Ni-Cu icosahedral and cuboctahedral free nanoclusters of different sizes by the ``free-energy concentration expansion method'' are used for evaluating pertinent cluster thermodynamic functions. Compared to stable surface segregated ``magic-number'' structures, at intermediate overall compositions the cluster system is expected to separate into these ``phases.'' A Schottky-type heat-capacity anomaly is predicted and attributed to atomic exchange (e.g., desegregation) excitation processes. Its measurement can elucidate the cluster segregation energetics." @default.
• W2086247712 created "2016-06-24" @default.
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• W2086247712 date "2005-03-28" @default.
• W2086247712 modified "2023-10-17" @default.
• W2086247712 title "Prediction of intercluster separation and Schottky-type heat-capacity contribution in surface-segregated binary and ternary alloy nanocluster systems" @default.
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• W2086247712 doi "https://doi.org/10.1103/physrevb.71.125426" @default.
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