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- W2086284217 abstract "All three isomers of 4,7-dimethylpentacyclo[6.3.0.02,6.03,10.05,9] undecane-4,7-diol have been prepared and their X-ray structures determined as part of a crystal engineering study into the prediction of new inclusion hosts. The syn,syn-isomer 9 forms a double-stranded hydrogen-bonded lattice type [C13H18O2, P21/c, a 6.3005(5), b 22.372(1), c 7.5313(6)Å, β 96.748(4)°, Z 4, R 0.052] and the anti,syn isomer 10 forms a hydrogen-bonded layer lattice [P21/c, a12.005(1), b 6.3979(7), c14.955(1)Å, β112.767(3)°, Z 4, R 0.045]. In contrast, the anti,anti-isomer 11 is a new member of the helical tubuland diol host family [(C13H18O2)3·(C3D6O)1.2, P3121, a12.4957(6), c 7.3076(3), Z 1, R 0.039] containing parallel guest-containing canals with trefoil-shaped cross-section of area 25.4 Å2." @default.
- W2086284217 created "2016-06-24" @default.
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- W2086284217 date "1993-01-01" @default.
- W2086284217 modified "2023-10-14" @default.
- W2086284217 title "A trishomocubyl helical tubuland diol inclusion host" @default.
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- W2086284217 doi "https://doi.org/10.1039/p29930000937" @default.
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