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- W2086292999 abstract "Reaction of [TiCl{3}(O-i-Pr)] with [Li(CNN)]{2} (CNN = monoanionic C{6}H{4}(CH{2}N(Me)CH{2}CH{2}NMe{2})-2) in 2:1 molar ratio in toluene at -78}o{C afforded [TiCl{2}(CNN)(O-i-Pr)] as a 3:2 molar mixture of two stereoisomers. The stereoisomers differ by the mutual position of the chloro and alkoxy ligands. Molecular modelling calculations and an X-ray analysis of one of the stereoisomers indicated that the alkoxy ligand exhibits a strong trans preference to the weakest @p-donating ligated atom, i.e., the N(Me{2}) atom of the CNN ligand. The molecular structure of this stereoisomer, as determined by X-ray analysis, involves an octahedral titanium center with an @h}3{-fac-C, N,N'-bonded CNN ligand. A strong M-O(alkoxy) interaction is illustrated by an almost linear M-O-C bond angle of 172.4(2)}o{. As a result of the pseudofacially bonded CNN ligand, the titanium center as well as the central N-donor center are stereogenic resulting in the formation of two enantiomers. A (CNN)titanium(IV) dimethyl complex is accessible via reaction of 1 with two equivalents of MeLi and contains likewise an @h}3{-fac-C,N,N'-bonded CNN ligand." @default.
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- W2086292999 date "1997-12-01" @default.
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- W2086292999 title "Aryltitanium(IV) complexes with the η3-C,N,N′-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]−. The X-ray crystal structure of [TiCl2(CNN)(O-i-Pr)]" @default.
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- W2086292999 doi "https://doi.org/10.1016/s0022-328x(97)00475-0" @default.
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