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• W2086306558 abstract "The combustion of CH4 in fuel-rich, CH4/O2/Ar = 9/1/90, mixtures was studied by infrared (IR) laser kinetic absorption spectroscopy behind incident shock waves with 1800 < TK < 2700 at total densities of ∼1.2 × 10−6 mol cm−3. Computer simulations using a 63-reaction mechanism were used to identify the elementary reactions that determined the data parameters and to investigate the consequences of various rate-constant assumptions. An experimental data base from the literature was also used to test the mechanism and rate constants over a wide variety of conditions of temperature, pressure, and equivalence ratio. Rate-constant expressions are suggested for CH2 + CH3 = C2H4 + H and CH3 + O2 = CH2O + OH." @default.
• W2086306558 created "2016-06-24" @default.
• W2086306558 creator A5005705944 @default.
• W2086306558 creator A5025355734 @default.
• W2086306558 date "1978-01-01" @default.
• W2086306558 modified "2023-09-28" @default.
• W2086306558 title "Combustion of methane in fuel-rich mixtures" @default.
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• W2086306558 doi "https://doi.org/10.1016/0010-2180(78)90089-5" @default.
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