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- W2086325293 abstract "Infrared multiple photon dissociation (IRMPD) spectroscopy was used to study formation of b2+ from nicotinyl-glycine-glycine-methyl ester (NicGGOMe). IRMPD shows that NicGGOMe is protonated at the pyridine ring of the nicotinyl group, and more importantly, that b2+ from NicGGOMe is not protonated at the oxazolone ring, as would be expected if the species were generated on the conventional bn+/yn+ oxazolone pathway, but at the pyridine ring instead. IRMPD data support a hypothesis that formation of b2+ from NicGGOMe involves mobilization and transfer of an amide position proton during the fragmentation reaction." @default.
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- W2086325293 date "2009-07-01" @default.
- W2086325293 modified "2023-10-06" @default.
- W2086325293 title "Spectroscopic evidence for mobilization of amide position protons during CID of model peptide ions" @default.
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- W2086325293 doi "https://doi.org/10.1016/j.jasms.2009.06.007" @default.
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