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- W2086343791 endingPage "6764" @default.
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- W2086343791 abstract "The 1,9-ethanoiminomethano-bridged tetrahydrodibenzo[b,d]-furan 2, a non-natural isomer of the alkaloid (−)-galanthamine (1) varying in the manner in which the D-ring is annulated to the ABC-core, has been prepared in racemic form. The synthetic sequence starts with the cyclopropane 3 and involves intramolecular Heck alkenylation and radical-based Smiles rearrangement reactions as key steps. Unlike natural product 1, but as predicted by docking studies, compound 2 is not a potent inhibitor of acetylcholine esterase." @default.
- W2086343791 created "2016-06-24" @default.
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- W2086343791 date "2014-07-09" @default.
- W2086343791 modified "2023-10-17" @default.
- W2086343791 title "Synthesis of a D-Ring Isomer of Galanthamine via a Radical-Based Smiles Rearrangement Reaction" @default.
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- W2086343791 doi "https://doi.org/10.1021/jo501255c" @default.
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