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• W2086350697 abstract "Vacuum ultraviolet (VUV) irradiation of acetamide has been monitored by Fourier transform infrared spectroscopy in argon matrix at 10 K. Several primary photoproducts, including HNCO ∶ CH4 and CO ∶ CH3NH2 molecular complexes, and acetimidic acid, which is reported for the first time, were characterized. The acetimidic acid identification was based on comparison between the experimental and theoretical (B3LYP) infrared spectra. Acetimidic acid is found in argon matrix in the (s-Z)–(E) and (s-Z)–(Z) configurations. It is also an intermediate in the VUV decomposition process, its dehydration leads to the formation of CH3CN ∶ H2O molecular complex. The assignment of the complex was achieved by co-depositing the pairs of respective species and by ab initio calculation." @default.
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• W2086350697 date "2007-01-01" @default.
• W2086350697 modified "2023-09-27" @default.
• W2086350697 title "Photochemical dehydration of acetamide in a cryogenic matrix" @default.
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• W2086350697 doi "https://doi.org/10.1039/b617586d" @default.
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