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- W2086352891 startingPage "3627" @default.
- W2086352891 abstract "Title complexes of t- and p-[Co(A)(tren)]Cl2·H2O, t- and p-[Co(C)(tren)]Cl·H2O, cis-β1 and β2-[Co(A)(trien)]Cl2·2H2O, cis-β1-[Co(C)(trien)]Cl·H2O, cis-β1-[Co(D)(trien)]Cl·H2O, [Co(A)(en)2]Cl2·H2O, [Co(C)(en)2]Cl·H2O, and [Co(D)(en)2]Cl·H2O have been obtained from a reaction mixture of [CoCl2L]Cl·H2O [L: tren, trien, or (en)2], Ag2O, and salicylamide. (Remark: Graphics omitted.) Separations of the A-, C-, and D-type complexes, and of the geometrical isomers of t- and p- or cis-β1 and β2 were attempted by using Dowex 50W-X2 column chromatography. Distinction of the A-, C-, and D-type complexes is described in the IR, 1H, 13C NMR, and absorption spectra; the solubility in DMSO; and the electric conductivities in aqueous solutions. The formation ratio of the A-, C-, and D-type complexes has been dependent upon the pH of the reaction mixture. The chemical shifts (δ=113–115) of the C-l carbon signals for the A-type complexes are at a higher field than those (δ=117–122) of the C- and D-type complexes. The e valu..." @default.
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- W2086352891 date "1991-12-01" @default.
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- W2086352891 title "Cobalt(III) Complexes with [N6−nXn]-Type Ligands. VII. Preparation and Properties of Isomers of the (Salicylamidato)cobalt(III) Complexes with Tris(2-aminoethyl)amine, Triethylenetetramine, and Ethylenediamine Ligands" @default.
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- W2086352891 doi "https://doi.org/10.1246/bcsj.64.3627" @default.
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