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- W2086354857 abstract "Solutions of 1-methylnaphthalene in membrane-filtered natural seawater were exposed to sunlight in quartz vessels. The same solutions in amber glass vessels served as a dark control. Photo-oxidation products identified were: 1-naphthaldehyde, 1-hydroxymethylnaphthalene, 3-methyl-1(3H)-isobenzofuranone, glyoxal, and traces of 4-methyl- and 7-methyl-1(3H)-isobenzofuranone, these last two compounds being tentatively identified on the basis of their mass spectra. The products with an unchanged carbon skeleton suggest sensitizer-mediated hydrogen abstraction. The reaction sequence leading to the formation of glyoxal and the isobenzofuranones is proposed as starting with the addition of singlet molecular oxygen to the aromatic double bond system. After 10 days of exposure to summer sunlight at Kiel, Germany (54° 20′ N), the concentration of 1-methylnaphthalene decreased to approximately 50% of the initial value, whereas the concentration in the dark control remained essentially unchanged. The intensities of impinging solar UVA and UVB radiation were recorded to enable the extension of the observed photo-oxidation rate to light regimes deviating from those of the experiment." @default.
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- W2086354857 date "1997-08-01" @default.
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- W2086354857 title "Photo-oxidation of 1-methylnaphthalene dissolved in seawater and exposed to sunlight under quasi-environmental conditions" @default.
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- W2086354857 doi "https://doi.org/10.1016/s1010-6030(97)00079-8" @default.
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