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- W2086360076 abstract "A homogeneous catalyst system for the asymmetric cis-hydrogenation of 2,5-disubstituted furans leading to 2‘,3‘-dideoxynucleoside analogues is described. Best enantioselectivities (ee values of up to 72%) were obtained with cationic rhodium complexes ligated by diphospholanes of the butiphane family. The selectivity of the hydrogenation was reversed by the addition of a base or a polar protic solvent in certain cases. Ferrocene- and proline-based systems gave significant, but lower, ee values." @default.
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- W2086360076 date "2006-08-01" @default.
- W2086360076 modified "2023-10-16" @default.
- W2086360076 title "Asymmetric Homogeneous Hydrogenation of 2,5-Disubstituted Furans" @default.
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- W2086360076 doi "https://doi.org/10.1021/ol061681r" @default.
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