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- W2086388410 startingPage "983" @default.
- W2086388410 abstract "Interactions of CoCl2 with K{M(OPri)6} in 1:2 molar ratio in PriOH and C6H6 result in products with the composition [Co{M(OPri)6}b42] (M=Nb or Ta) in quantitative yields. Interchange reactions of these isopropoxide derivatives with alcohols of varying steric bulk (e.g., MeOH, EtOH, PrnOH, BunOH, and ButOH, or AmtOH) yield derivatives of composition, [Co{M(OR)6}2] (R=Me, Et, Prn, and Bus); [Co{M(OPri)3(OBus)3}2]; [Co{M(OPri)5(OBut)}2] and [Co{M(OPri)2(OR)4}2] (R=But or Amt). All these novel compounds have been characterized by elemental analyses and molecular weight determinations as well as by infrared, visible spectral and magnetic studies." @default.
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- W2086388410 date "1988-03-01" @default.
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- W2086388410 title "Synthesis, Reactions, Spectral (IR and Visible) and Magnetic Studies of Bimetallic Alkoxides Containing Co(μ-OR)3M(M=Nb or Ta) Bridging Units" @default.
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- W2086388410 doi "https://doi.org/10.1246/bcsj.61.983" @default.
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