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• W2086403974 abstract "Tip-enhanced Raman spectroscopy (TERS) is based on the optical excitation of localized surface plasmons in the tip-substrate cavity, which provides a large but local field enhancement near the tip apex. We report on TERS with smooth single crystalline surfaces as substrates. The adsorbates were ${mathrm{C}mathrm{N}}^{ensuremath{-}}$ ions at Au(111) and malachite green isothiocyanate (MGITC) molecules at Au(111) and Pt(110) using either Au or Ir tips. The data analysis yields Raman enhancements of about $4ifmmodetimeselsetexttimesfi{}{10}^{5}$ for ${mathrm{C}mathrm{N}}^{ensuremath{-}}$ and up to ${10}^{6}$ for MGITC at Au(111) with a Au tip, probing an area of less than 100 nm radius." @default.
• W2086403974 created "2016-06-24" @default.
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• W2086403974 date "2004-03-02" @default.
• W2086403974 modified "2023-10-18" @default.
• W2086403974 title "Nanoscale Probing of Adsorbed Species by Tip-Enhanced Raman Spectroscopy" @default.
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• W2086403974 doi "https://doi.org/10.1103/physrevlett.92.096101" @default.
• W2086403974 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15089490" @default.
• W2086403974 hasPublicationYear "2004" @default.
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