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- W2086429568 abstract "Fraser suggested that, in the expression for the transition probability, the electronic transition moment and the Franck-Condon overlap integral are separable, both depending on the initial and final quantum numbers of the band. A good approximation in many cases, Fraser's formula is inaccurate for certain molecular bands. An improved formula is found including, in addition to the electronic transition moment and the Franck-Condon overlap integral, a third factor which also depends on the vibrational quantum numbers. Using this formula, the degree of accuracy of Fraser's approximation is calculated. An example shows that it may be of the order of 20%, thus justifying the use of the `correction' factor." @default.
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- W2086429568 date "1965-11-01" @default.
- W2086429568 modified "2023-10-18" @default.
- W2086429568 title "An improved formula for the vibrational transition probabilities of diatomic molecules" @default.
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- W2086429568 doi "https://doi.org/10.1088/0370-1328/86/5/316" @default.
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