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- W2086476732 abstract "Quantum efficiencies and ultrafast dynamics of the ring-closure and ring-opening reaction of a trifluorinated dicyclopropyl indolylfulgide with improved photostability are investigated by stationary and ultrafast absorption spectroscopy. The ring-closure reaction occurs on the time scale of 200 fs and is found to be temperature independent (T = 287–333 K). However, an activated behaviour is observed for the ring-opening reaction. A comparison with the corresponding non-substituted indolylfulgide shows that the dicyclopropyl group favours the open isomer via lower cyclisation and higher cycloreversion quantum efficiencies and faster dynamics of the ring-opening reaction." @default.
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- W2086476732 date "2009-08-01" @default.
- W2086476732 modified "2023-09-26" @default.
- W2086476732 title "Stability and reaction dynamics of trifluorinated indolylfulgides" @default.
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- W2086476732 doi "https://doi.org/10.1016/j.cplett.2009.07.013" @default.
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