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- W2086511163 abstract "Recently observed non-proton hydrate ions observed at 37 km by Arnold, Bohringer and Henschen are interpreted as being protonated sodium hydroxide cluster ions of the form NaOH2+ (H2O)n(NaOH)m. Values of n from 0 to 4 and m from 0 to 2 allow an interpretation of all seven unidentified NPH ions reported by Arnold et al. The sodium oxide molecules believed to exist below the well-known sodium layer around 90 km are presumed to convert to the more stable NaOH molecules below ∼ 40 km where the OH/H and HO2/H concentration ratios become very large. The very large proton affinity of NaOH (∼248 kcal mol−1) virtually assures proton transfer from the H+(H2O)n ions that are produced in the stratosphere and observed to be dominant above ∼ 40 km. The possible role of other metallic species in stratospheric ion chemistry is briefly discussed." @default.
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- W2086511163 date "1978-12-01" @default.
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- W2086511163 title "Sodium hydroxide ions in the stratosphere" @default.
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- W2086511163 doi "https://doi.org/10.1029/gl005i012p01035" @default.
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