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- W2086536675 abstract "A white insoluble 1:1 complex is formed between stannic chloride and α,α′-dimethoxy-p-xylene (DMPX) when the Friedel-Crafts copolymerisation of DMPX and benzene is carried out in a series of solvents using stannic chloride as catalyst. As the reaction proceeds, the precipitate dissolves, being converted to a 1:1 and later a 1:2 complex of stannic chloride and methanol, the latter being a product of the reaction. The 1:1 stannic chloride:methanol complex is an active catalyst for the polymerisation while the 1:2 complex is relatively inactive. The rate of the reaction is also strongly dependent upon the dielectric constant of the medium. For these reasons, a precise quantitative investigation of the kinetics of the polymerisation will be almost impossible but experimental conditions are specified whereby a partial investigation may be made for comparison with the SnCl4/benzene/di(chloromethyl) benzene system previously studied." @default.
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- W2086536675 date "1976-01-01" @default.
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- W2086536675 title "Friedel-crafts polymerisations with α,α′-dimethoxy-p-xylene—I The initiation step with stannic chloride as catalyst" @default.
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- W2086536675 doi "https://doi.org/10.1016/0014-3057(76)90030-6" @default.
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