FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086576116> ?p ?o ?g. }

• W2086576116 endingPage "1591" @default.
• W2086576116 startingPage "1583" @default.
• W2086576116 abstract "The rate constant for the reaction of HO2 with O3 was measured using a turbulent flow reactor with tunable diode laser absorption detection of HO2. Two separate methods were used to determine k1 from the pseudo-first-order decay of HO2 in excess O3. The isotopic labeling method used H18O2 in excess 16O3 to avoid reformation of the reactant. The OH scavenger method used trifluorochloroethylene to remove the OH product and prevent re-formation of HO2. The turbulent flow reactor allowed measurements at temperatures between 297 and 197 K at total pressures from 80 to 175 Torr, spanning a wide range of stratospheric conditions. The temperature-dependent rate constant is given by the three-term expression k1(T) = {(103 ± 57) exp[−(1323 ± 160)/T] + 0.88} × 10-15 cm3 molecule-1 s-1, reflecting its non-Arrhenius behavior at low temperatures. These results demonstrate that the catalytic destruction of lower stratospheric O3 by HOx radicals (OH and HO2) may proceed faster than current models predict. The rate constant at 295 K is (2.0 ± 0.2) × 10-15 cm3 molecule-1 s-1." @default.
• W2086576116 created "2016-06-24" @default.
• W2086576116 creator A5010198153 @default.
• W2086576116 creator A5015278922 @default.
• W2086576116 creator A5069132029 @default.
• W2086576116 creator A5074793430 @default.
• W2086576116 creator A5090247210 @default.
• W2086576116 date "2000-12-14" @default.
• W2086576116 modified "2023-09-23" @default.
• W2086576116 title "Rate Constant Measurements for the Reaction of HO₂ with O₃ from 200 to 300 K Using a Turbulent Flow Reactor" @default.
• W2086576116 cites W1966763064 @default.
• W2086576116 cites W1975734984 @default.
• W2086576116 cites W1997668985 @default.
• W2086576116 cites W2006592599 @default.
• W2086576116 cites W2013841078 @default.
• W2086576116 cites W2013979323 @default.
• W2086576116 cites W2023546252 @default.
• W2086576116 cites W2043426262 @default.
• W2086576116 cites W2043575676 @default.
• W2086576116 cites W2045046598 @default.
• W2086576116 cites W2045700598 @default.
• W2086576116 cites W2057928902 @default.
• W2086576116 cites W2068343924 @default.
• W2086576116 cites W2077005062 @default.
• W2086576116 cites W2077835777 @default.
• W2086576116 cites W2091046256 @default.
• W2086576116 cites W2134000548 @default.
• W2086576116 cites W2171968446 @default.
• W2086576116 cites W2498140625 @default.
• W2086576116 cites W278531595 @default.
• W2086576116 cites W2952929012 @default.
• W2086576116 cites W320211004 @default.
• W2086576116 cites W4248587126 @default.
• W2086576116 doi "https://doi.org/10.1021/jp002383t" @default.
• W2086576116 hasPublicationYear "2000" @default.
• W2086576116 type Work @default.
• W2086576116 sameAs 2086576116 @default.
• W2086576116 citedByCount "34" @default.
• W2086576116 countsByYear W20865761162012 @default.
• W2086576116 countsByYear W20865761162013 @default.
• W2086576116 countsByYear W20865761162015 @default.
• W2086576116 countsByYear W20865761162016 @default.
• W2086576116 countsByYear W20865761162018 @default.
• W2086576116 countsByYear W20865761162023 @default.
• W2086576116 crossrefType "journal-article" @default.
• W2086576116 hasAuthorship W2086576116A5010198153 @default.
• W2086576116 hasAuthorship W2086576116A5015278922 @default.
• W2086576116 hasAuthorship W2086576116A5069132029 @default.
• W2086576116 hasAuthorship W2086576116A5074793430 @default.
• W2086576116 hasAuthorship W2086576116A5090247210 @default.
• W2086576116 hasConcept C113196181 @default.
• W2086576116 hasConcept C121332964 @default.
• W2086576116 hasConcept C139066938 @default.
• W2086576116 hasConcept C147789679 @default.
• W2086576116 hasConcept C148898269 @default.
• W2086576116 hasConcept C172120300 @default.
• W2086576116 hasConcept C178790620 @default.
• W2086576116 hasConcept C185592680 @default.
• W2086576116 hasConcept C196558001 @default.
• W2086576116 hasConcept C30646810 @default.
• W2086576116 hasConcept C62520636 @default.
• W2086576116 hasConcept C86183883 @default.
• W2086576116 hasConcept C93391505 @default.
• W2086576116 hasConcept C95121573 @default.
• W2086576116 hasConcept C97355855 @default.
• W2086576116 hasConceptScore W2086576116C113196181 @default.
• W2086576116 hasConceptScore W2086576116C121332964 @default.
• W2086576116 hasConceptScore W2086576116C139066938 @default.
• W2086576116 hasConceptScore W2086576116C147789679 @default.
• W2086576116 hasConceptScore W2086576116C148898269 @default.
• W2086576116 hasConceptScore W2086576116C172120300 @default.
• W2086576116 hasConceptScore W2086576116C178790620 @default.
• W2086576116 hasConceptScore W2086576116C185592680 @default.
• W2086576116 hasConceptScore W2086576116C196558001 @default.
• W2086576116 hasConceptScore W2086576116C30646810 @default.
• W2086576116 hasConceptScore W2086576116C62520636 @default.
• W2086576116 hasConceptScore W2086576116C86183883 @default.
• W2086576116 hasConceptScore W2086576116C93391505 @default.
• W2086576116 hasConceptScore W2086576116C95121573 @default.
• W2086576116 hasConceptScore W2086576116C97355855 @default.
• W2086576116 hasIssue "9" @default.
• W2086576116 hasLocation W20865761161 @default.
• W2086576116 hasOpenAccess W2086576116 @default.
• W2086576116 hasPrimaryLocation W20865761161 @default.
• W2086576116 hasRelatedWork W1968562671 @default.
• W2086576116 hasRelatedWork W1989071799 @default.
• W2086576116 hasRelatedWork W2055771497 @default.
• W2086576116 hasRelatedWork W2061169181 @default.
• W2086576116 hasRelatedWork W2080078138 @default.
• W2086576116 hasRelatedWork W2081276680 @default.
• W2086576116 hasRelatedWork W2168444623 @default.
• W2086576116 hasRelatedWork W2192119194 @default.
• W2086576116 hasRelatedWork W4210669284 @default.
• W2086576116 hasRelatedWork W4251476506 @default.
• W2086576116 hasVolume "105" @default.
• W2086576116 isParatext "false" @default.
• W2086576116 isRetracted "false" @default.
• W2086576116 magId "2086576116" @default.

• next