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- W2086584967 abstract "A magnetically recoverable catalyst consisting of copper nanoparticles (CuNPs) on nanosized silica-coated maghemite is presented. The catalyst has been prepared under mild conditions by mixing the magnetic support with a freshly prepared suspension of CuNPs obtained by fast reduction of anhydrous CuCl2 with lithium sand and a catalytic amount of DTBB (4,4′-di-tert-butylbiphenyl) as electron carrier. This copper-based catalyst has shown to be very efficient in the N-(hetero)arylation of imidazole using (hetero)aryl bromides and iodides as arylating agents under ligand-free conditions. The catalyst is easily recovered by means of an external magnet and can be reutilized in three N-arylation cycles without apparent loss of catalytic activity." @default.
- W2086584967 created "2016-06-24" @default.
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- W2086584967 creator A5020807068 @default.
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- W2086584967 date "2014-09-01" @default.
- W2086584967 modified "2023-10-06" @default.
- W2086584967 title "Synthesis of N-aryl imidazoles catalyzed by copper nanoparticles on nanosized silica-coated maghemite" @default.
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- W2086584967 doi "https://doi.org/10.1016/j.tet.2014.04.003" @default.
- W2086584967 hasPublicationYear "2014" @default.
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