Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086599147> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W2086599147 endingPage "235" @default.
- W2086599147 startingPage "231" @default.
- W2086599147 abstract "Abstract Using the synthetic method, the solubility of diosgenin in 1-hexanol and 1-heptanol was measured at temperatures from 300 K to 329 K by a laser monitoring observation technique at atmospheric pressure. The solubility data were correlated by semi-empirical equations, such as the Apelblat equation, λh model and the ideal model, which agreed well with experimental results. The fusion enthalpy and the melting point determined by differential scanning calorimeter (DSC), are −34064.2 J · mol−1 and 207.09 °C for diosgenin. With collection of over 14 solvents from different references, the NRTL thermodynamic model as one of the activity coefficient models was used to correlate and predict the solubility of diosgenin. The solubility calculated for all solvents showed good agreement with the experimental results within the temperature range studied. Additionally, the solubility of diosgenin in 14 solvents is also investigated at T = 308.15 K, the results of which indicated that solubility of diosgenin in n-alkanols tends to increase with increasing alkanol chain length from methanol to 1-heptanol and n-alkanols presented higher solubility than heterogeneous alcohols for diosgenin, such as 1-butanol > isobutyl alcohol > tert-butanol and 1-propanol > isopropanol. It also shows that solubility of diosgenin decreases with the increasing polarity of solvents. Its corresponding (solid + liquid) equilibrium data will provide essential support for industrial design and further detailed theoretical studies." @default.
- W2086599147 created "2016-06-24" @default.
- W2086599147 creator A5001293578 @default.
- W2086599147 creator A5028807063 @default.
- W2086599147 creator A5035147892 @default.
- W2086599147 creator A5040790264 @default.
- W2086599147 creator A5070749354 @default.
- W2086599147 date "2014-04-01" @default.
- W2086599147 modified "2023-10-16" @default.
- W2086599147 title "Application of the NRTL method to correlate solubility of diosgenin" @default.
- W2086599147 cites W1970892132 @default.
- W2086599147 cites W1971320013 @default.
- W2086599147 cites W1977118315 @default.
- W2086599147 cites W1994726616 @default.
- W2086599147 cites W2013162139 @default.
- W2086599147 cites W2016964174 @default.
- W2086599147 cites W2019987110 @default.
- W2086599147 cites W2072476365 @default.
- W2086599147 cites W2171250148 @default.
- W2086599147 cites W2951050136 @default.
- W2086599147 doi "https://doi.org/10.1016/j.jct.2013.12.020" @default.
- W2086599147 hasPublicationYear "2014" @default.
- W2086599147 type Work @default.
- W2086599147 sameAs 2086599147 @default.
- W2086599147 citedByCount "18" @default.
- W2086599147 countsByYear W20865991472014 @default.
- W2086599147 countsByYear W20865991472015 @default.
- W2086599147 countsByYear W20865991472017 @default.
- W2086599147 countsByYear W20865991472018 @default.
- W2086599147 countsByYear W20865991472019 @default.
- W2086599147 countsByYear W20865991472020 @default.
- W2086599147 countsByYear W20865991472021 @default.
- W2086599147 countsByYear W20865991472022 @default.
- W2086599147 countsByYear W20865991472023 @default.
- W2086599147 crossrefType "journal-article" @default.
- W2086599147 hasAuthorship W2086599147A5001293578 @default.
- W2086599147 hasAuthorship W2086599147A5028807063 @default.
- W2086599147 hasAuthorship W2086599147A5035147892 @default.
- W2086599147 hasAuthorship W2086599147A5040790264 @default.
- W2086599147 hasAuthorship W2086599147A5070749354 @default.
- W2086599147 hasConcept C121332964 @default.
- W2086599147 hasConcept C155574463 @default.
- W2086599147 hasConcept C170961132 @default.
- W2086599147 hasConcept C178790620 @default.
- W2086599147 hasConcept C184651966 @default.
- W2086599147 hasConcept C185592680 @default.
- W2086599147 hasConcept C2776601336 @default.
- W2086599147 hasConcept C40117563 @default.
- W2086599147 hasConcept C43617362 @default.
- W2086599147 hasConcept C97355855 @default.
- W2086599147 hasConceptScore W2086599147C121332964 @default.
- W2086599147 hasConceptScore W2086599147C155574463 @default.
- W2086599147 hasConceptScore W2086599147C170961132 @default.
- W2086599147 hasConceptScore W2086599147C178790620 @default.
- W2086599147 hasConceptScore W2086599147C184651966 @default.
- W2086599147 hasConceptScore W2086599147C185592680 @default.
- W2086599147 hasConceptScore W2086599147C2776601336 @default.
- W2086599147 hasConceptScore W2086599147C40117563 @default.
- W2086599147 hasConceptScore W2086599147C43617362 @default.
- W2086599147 hasConceptScore W2086599147C97355855 @default.
- W2086599147 hasLocation W20865991471 @default.
- W2086599147 hasOpenAccess W2086599147 @default.
- W2086599147 hasPrimaryLocation W20865991471 @default.
- W2086599147 hasRelatedWork W2067693715 @default.
- W2086599147 hasRelatedWork W2085001569 @default.
- W2086599147 hasRelatedWork W2094639770 @default.
- W2086599147 hasRelatedWork W2404301061 @default.
- W2086599147 hasRelatedWork W2538967080 @default.
- W2086599147 hasRelatedWork W2546784243 @default.
- W2086599147 hasRelatedWork W2998550365 @default.
- W2086599147 hasRelatedWork W3093823893 @default.
- W2086599147 hasRelatedWork W3108383816 @default.
- W2086599147 hasRelatedWork W3133219848 @default.
- W2086599147 hasVolume "71" @default.
- W2086599147 isParatext "false" @default.
- W2086599147 isRetracted "false" @default.
- W2086599147 magId "2086599147" @default.
- W2086599147 workType "article" @default.