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- W2086619547 abstract "The fluorescence of PPS film and model compounds were measured, and changes were observed during thermal curing. Fluorescences from both intramolecular conjugated sites and from ground state intermolecular aggregates were observed. The intensities of these fluorescences increase during annealing due to conformational rearrangement and increase in molecular packing. The formation of intermolecular aggregates could be one reason for coloration of PPS film during thermal treatment. The rates of increase of the fluorescence intensity are different between samples annealed in air and in nitrogen. The effect of the atmosphere is believed to result from the change in the extent of chemical degradation of the PPS during thermal treatment as well as physical change of the polymer solid state." @default.
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- W2086619547 date "1993-01-01" @default.
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- W2086619547 title "Degradation of sulfur-containing aromatic polymers (II): Change in fluorescence spectra of polyphenylenesulfide (PPS) during annealing" @default.
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