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- W2086699102 abstract "A series of V(IV)O bis chelated complexes of alpha-hydroxycarboxylic acids with a 2(COO(-), O(-)) coordination set was analyzed by electronic absorption and EPR spectroscopy in aqueous solution. All the complexes exhibit a square-pyramidal geometry distorted toward trigonal bipyramid. The influence of the distortion of the geometry, as deduced from the steric hindrance produced by the substituents at the alpha-carbon atom of the ligands, on the spectroscopic parameters has been studied. The observed trends were related to the electronic structure of the metal ion in the distorted geometry." @default.
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- W2086699102 date "2003-06-01" @default.
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- W2086699102 title "Electronic Structure of Oxovanadium(IV) Complexes of α-Hydroxycarboxylic Acids" @default.
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- W2086699102 doi "https://doi.org/10.1021/ic0260567" @default.
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