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- W2086702898 abstract "The transformation of dicalcium phosphate dihydrate into octacalcium phosphate (OCP) under carefully controlled conditions in calcium phosphate solutions of pH 6.4–7.0 has been investigated using a pH-stat technique. During the initial dissolution of DCPD, with roughening of the crystal surface, the nucleation of OCP takes place and transformation continues with an appreciable consumption of alkali, to maintain the pH, during the growth of these OCP nuclei. In solutions undersaturated with respect to DCPD, the transformation reactions are facilitated due to the increased DCPD surface roughness produced by the more extensive initial dissolution. An increase in the amount of DCPD seed crystals also increases the rate of OCP formation. The transformation is markedly inhibited by the presence of magnesium ions which have been shown in previous constant composition experiments to have a greater influence in reducing the rate of OCP crystal growth as compared with that of DCPD." @default.
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- W2086702898 title "The phase transformation of calcium phosphate dihydrate into octacalcium phosphate in aqueous suspensions" @default.
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