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- W2086746130 abstract "Diastereoselective addition of nucleophiles to 1-(RCO)-substituted tricarbonyη4-cyclohexadiene)iron(0) complexes, and a diastereoselective acid-induced rearrangement to form 1-(branched alkyl)-substituted tricarbonyl(η5-cyclohexadienyl)iron(1+) salts, are described. Stereocontrol in the rearrangement has been studied, and HPF6, Ac2O has been shown to be the most suitable acid to promote diastereoselectivity. The product was reacted with LiCH(SO2Ph)2, completing one turn of an iterative cycle which formed a chiral centre at each step." @default.
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- W2086746130 date "1997-01-01" @default.
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- W2086746130 title "More efficient iterative uses of tricarbonyliron complexes are possible by diastereoselective formation of η5-cyclohexadienyl complexes" @default.
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- W2086746130 doi "https://doi.org/10.1016/s0040-4039(96)02360-x" @default.
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