Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086747002> ?p ?o ?g. }
- W2086747002 endingPage "5696" @default.
- W2086747002 startingPage "5693" @default.
- W2086747002 abstract "Abstract A new method for titanium‐catalyzed reductive umpolung reactions is reported that overcomes the traditional requirement for a stoichiometric metallic reductant. With N , N ′‐disilylated tetramethyldihydropyrazine as a potent organic reducing agent, reductive carbonyl–nitrile, enone–acrylonitrile and pinacol coupling reactions can be achieved in good yields and stereoselectivities. [Cp 2 TiI 2 ] is a superior catalyst to [Cp 2 TiCl 2 ], which is rationalized by a faster generation of the active catalyst [Cp 2 TiI]. A mechanism is proposed that is in agreement with the experimental results." @default.
- W2086747002 created "2016-06-24" @default.
- W2086747002 creator A5030606533 @default.
- W2086747002 creator A5033292901 @default.
- W2086747002 creator A5040667086 @default.
- W2086747002 date "2015-02-25" @default.
- W2086747002 modified "2023-10-18" @default.
- W2086747002 title "Titanium-Catalyzed Reductive Umpolung Reactions with a Metal-Free Terminal Reducing Agent" @default.
- W2086747002 cites W1596247705 @default.
- W2086747002 cites W1989866026 @default.
- W2086747002 cites W1999507813 @default.
- W2086747002 cites W2004905821 @default.
- W2086747002 cites W2007820060 @default.
- W2086747002 cites W2009855090 @default.
- W2086747002 cites W2011253006 @default.
- W2086747002 cites W2030746315 @default.
- W2086747002 cites W2047167387 @default.
- W2086747002 cites W2049429051 @default.
- W2086747002 cites W2057367106 @default.
- W2086747002 cites W2058359620 @default.
- W2086747002 cites W2060961034 @default.
- W2086747002 cites W2061900057 @default.
- W2086747002 cites W2074865849 @default.
- W2086747002 cites W2077473690 @default.
- W2086747002 cites W2082458993 @default.
- W2086747002 cites W2083507391 @default.
- W2086747002 cites W2085073264 @default.
- W2086747002 cites W2092887523 @default.
- W2086747002 cites W2108274315 @default.
- W2086747002 cites W2113812987 @default.
- W2086747002 cites W2115798346 @default.
- W2086747002 cites W2117123115 @default.
- W2086747002 cites W2120952547 @default.
- W2086747002 cites W2123926845 @default.
- W2086747002 cites W2126492927 @default.
- W2086747002 cites W2129601941 @default.
- W2086747002 cites W2145661841 @default.
- W2086747002 cites W2157450848 @default.
- W2086747002 cites W2157532711 @default.
- W2086747002 cites W2159881043 @default.
- W2086747002 cites W2313683552 @default.
- W2086747002 cites W2325045839 @default.
- W2086747002 cites W2330285873 @default.
- W2086747002 cites W2332341745 @default.
- W2086747002 cites W2332356697 @default.
- W2086747002 cites W2949107950 @default.
- W2086747002 cites W2949462977 @default.
- W2086747002 cites W2949926463 @default.
- W2086747002 cites W2950167053 @default.
- W2086747002 cites W2950991387 @default.
- W2086747002 cites W3005130471 @default.
- W2086747002 cites W4247294945 @default.
- W2086747002 cites W67931553 @default.
- W2086747002 doi "https://doi.org/10.1002/chem.201500102" @default.
- W2086747002 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25712472" @default.
- W2086747002 hasPublicationYear "2015" @default.
- W2086747002 type Work @default.
- W2086747002 sameAs 2086747002 @default.
- W2086747002 citedByCount "45" @default.
- W2086747002 countsByYear W20867470022015 @default.
- W2086747002 countsByYear W20867470022016 @default.
- W2086747002 countsByYear W20867470022017 @default.
- W2086747002 countsByYear W20867470022018 @default.
- W2086747002 countsByYear W20867470022019 @default.
- W2086747002 countsByYear W20867470022020 @default.
- W2086747002 countsByYear W20867470022021 @default.
- W2086747002 countsByYear W20867470022022 @default.
- W2086747002 countsByYear W20867470022023 @default.
- W2086747002 crossrefType "journal-article" @default.
- W2086747002 hasAuthorship W2086747002A5030606533 @default.
- W2086747002 hasAuthorship W2086747002A5033292901 @default.
- W2086747002 hasAuthorship W2086747002A5040667086 @default.
- W2086747002 hasConcept C144082473 @default.
- W2086747002 hasConcept C15920480 @default.
- W2086747002 hasConcept C161790260 @default.
- W2086747002 hasConcept C178790620 @default.
- W2086747002 hasConcept C178907741 @default.
- W2086747002 hasConcept C185592680 @default.
- W2086747002 hasConcept C186423591 @default.
- W2086747002 hasConcept C21951064 @default.
- W2086747002 hasConcept C2776730140 @default.
- W2086747002 hasConcept C2778372188 @default.
- W2086747002 hasConcept C2779240715 @default.
- W2086747002 hasConcept C506065880 @default.
- W2086747002 hasConcept C521977710 @default.
- W2086747002 hasConcept C76164948 @default.
- W2086747002 hasConceptScore W2086747002C144082473 @default.
- W2086747002 hasConceptScore W2086747002C15920480 @default.
- W2086747002 hasConceptScore W2086747002C161790260 @default.
- W2086747002 hasConceptScore W2086747002C178790620 @default.
- W2086747002 hasConceptScore W2086747002C178907741 @default.
- W2086747002 hasConceptScore W2086747002C185592680 @default.
- W2086747002 hasConceptScore W2086747002C186423591 @default.
- W2086747002 hasConceptScore W2086747002C21951064 @default.
- W2086747002 hasConceptScore W2086747002C2776730140 @default.
- W2086747002 hasConceptScore W2086747002C2778372188 @default.
- W2086747002 hasConceptScore W2086747002C2779240715 @default.
- W2086747002 hasConceptScore W2086747002C506065880 @default.